纺织学报 ›› 2021, Vol. 42 ›› Issue (12): 188-195.doi: 10. 13475/j.fzxb.20201201008

• 综合述评 • 上一篇    下一篇

金属-有机骨架光催化降解染料的研究进展

李庆1(), 陈灵辉1, 李丹1, 吴志强1, 朱炜1, 樊增禄2   

  1. 1.西安工程大学 西安市纺织化工助剂重点实验室, 陕西 西安 710048
    2.功能性纺织材料及制品教育部重点实验室(西安工程大学), 陕西 西安 710048
  • 收稿日期:2020-12-04 修回日期:2021-09-10 出版日期:2021-12-15 发布日期:2021-12-29
  • 作者简介:李庆(1983—),男,副教授,博士。主要研究方向为金属-有机骨架的构筑及水环境修复。E-mail: liqingxpu1@163.com。
  • 基金资助:
    国家自然科学基金面上基金项目(22078253);陕西省重点研发项目(2020GY-276);陕西省教育厅服务地方专项(19JC016);西安市科技计划项目(2019217114GXRC007CG008-GXYD7.1);西安市碑林区科技计划项目(GX2003);国家级大学生创新训练计划项目(S202010709027)

Research progress in photocatalytic degradation of dyes using metal-organic frameworks

LI Qing1(), CHEN Linghui1, LI Dan1, WU Zhiqiang1, ZHU Wei1, FAN Zenglu2   

  1. 1. Xi'an Key Laboratory of Textile Chemical Engineering Auxiliaries, Xi'an Polytechnic University, Xi'an, Shaanxi 710048, China
    2. Key Laboratory of Functional Textile Material and Product(Xi'an Polytechnic University), Ministry of Education, Xi'an, Shaanxi 710048, China
  • Received:2020-12-04 Revised:2021-09-10 Published:2021-12-15 Online:2021-12-29

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摘要：

为促进金属-有机骨架(MOFs)在印染废水处理中的应用,对MOFs光催化降解染料的研究进展进行综述。阐述了MOFs的制备方法和空间结构的高可设计性,分析了提升MOFs可见光催化降解能力的策略:采用发色团修饰的有机配体来构筑高可见光响应性的MOFs;选取高可见光敏感的客体分子,通过物理吸附进入MOFs内部空腔或附着于其表面进行后修饰,构建出具有高可见光催化降解效能的MOFs复合材料。论述了提升MOFs循环使用能力即实用性的思路和方法,并分析了MOFs的光催化降解效果和染料降解产物。最后指出:开展基于高水稳定性MOFs的光敏后修饰研究,探索该材料与其他传统材料和技术结合,是推进MOFs在印染废水处理领域应用的努力方向。

关键词: 金属-有机骨架, 光催化降解, 染料, 可见光响应性, 稳定性, 染色废水, 废水处理

Abstract:

To promote the applications of metal-organic frameworks (MOFs) in dyeing wastewater treatment, research progress in using MOFs for photocatalytic degradation of dyes were reviewed. Preparation methods and high designability of their space structures were introduced, and strategies for enhancing their visible photocatalytic degradation capabilities were analyzed, including the use of organic ligands modified by chromophore to construct highly visible-light responsive MOFs. The review revealed that construction of MOFs composites with high visible-light catalytic degradation efficiency was achieved by selecting highly visible-light sensitive guest molecules and making them into the inner spaces or on the surface of MOFs for post-modification. Ideas and methods to improve the recycling ability of MOFs were discussed. The degradation performance and products of dye molecules were described and analyzed. Researches on photosensitive post-modification based on highly water stable MOFs, and exploration of the combination of this material with other traditional materials and technologies, have been suggested to be the direction for promoting the applications of MOFs in dyeing wastewater treatment.

Key words: metal-organic framework, photocatalytic degradation, dyes, visible-light responsiveness, stability, dyeing wastewater, wastewater treatment

中图分类号: 

  • TS190.2

图1

MOFs的制备方法"

图2

MOF-5与MOF-199的解构过程及拓扑结构"

图3

MOFs之间的带隙和光源(紫外光或可见光)比较以及染料敏化MOFs(宽带隙)系统中的电子转移途径"

图4

对苯二甲酸配体及其功能基团修饰"

图5

三原色光敏剂敏化的In-MOF对RB21高效而差异性的光催化降解能力"

图6

甲基改性配体构筑高水稳定Zr-MOF"

图7

高水稳定性的Zr-MOF复合材料可见光催化降解RB21"

图8

LC-MS检测的MB分子降解路径"

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